Diamond Coating with Potential for Glowing Tools

The illustrated single-stroke grinding roller manufactured by Sunnen Products Co. () is formed by mechanically adhering diamond abrasives to the tool body through a nickel plating process. (Photo courtesy of Diamond Tool Coating Company) Coating diamond coatings on tungsten carbide tools through a chemical vapor deposition (CVD) process can yield unparalleled advantages.
Chemical vapor deposition diamond retains the properties of natural diamonds. Its ultra-high hardness and elastic modulus guarantee very high dimensional stability and wear resistance. Like natural diamond, the chemical vapor deposition diamond has a low coefficient of friction, so the cutting force and power consumption are very low, the frictional heat is very low, and the formation of the built-up edge can be prevented when cutting.
These anti-corrosion coatings have a long service life when used for cutting corrosive polymers such as phenolic resins used for composite materials, and at the same time, they can also prevent corrosive damage by the cutting fluid.
Diamond-coated cutters are adept at processing abrasive non-metallic materials, non-ferrous metals and abrasive non-ferrous metals. However, the chemical instability of diamond and metal alloys containing iron, nickel or cobalt restricts the use of such coated tools in the cutting of non-ferrous alloys and superalloys.

Crystal chemical vapor deposition Diamond There are many coatings known as diamond, but chemical vapor deposition diamond is the only coating that uses 100% real diamond crystals.
Diamonds consist of pure carbon atoms arranged in a unique crystal orientation, thus possessing unique physical properties. At 9,000 to 10,000 Vickers, the hardness of crystalline diamond is almost twice that of amorphous and diamond-like coatings (DLC).
Amorphous diamond, or diamond-like coating, is a carbon film coated by a physical vapor deposition (PVD) process. These films are thinner than the chemical vapor deposition process coated diamond films.
They have no crystal structure and their lifetime is typically 10-15% of a chemical vapor deposited diamond coated tool.
Unlike the diamond tip coated with metal sintered polycrystalline diamond (PCD) on the tool, the chemical vapor deposition crystal diamond coating can protect the entire tool surface (including the tool with complex geometry) from the superhard material. The ability to coat this unique geometry allows chemical vapor deposited diamond coated tools to have more significant advantages over polycrystalline diamond tools, making the latter very expensive to
Machine.
A physical vapor deposition coating with a metal-nitride, such as titanium aluminum nitride (TiAlN), has a microhardness that is only 1/3 of that of crystalline diamond.
The advantages of chemical vapor deposition diamond coated drill bits compared with tip polycrystalline diamond drill bits have been fully demonstrated in carbon fiber drilling applications, and the single hole cost has been reduced by more than 70%. Chemical vapor deposited multi-layered diamond drills can machine 300 through holes in composites before burrs and delamination occur, while PCD tip drills can only machine 150 through holes.
Crystalline diamond is formed during the hot filament chemical vapor deposition process, which takes 20-40 hours. The temperature of 1,500°F (815.5°C) used in this process can prevent things other than solid carbide being coated. The precise pretreatment process requires 6% grade cemented carbide for optimal adhesion.
Without pretreatment, there is almost no chemical bond between diamond and carburized cemented carbide. However, the diamond can be embedded in the rough cemented carbide surface and adhered to the surface by the mechanical interlocking effect of cemented carbide and diamond.
A tool containing 10% cobalt can be coated, but additional processing is required to achieve good adhesion, making the coating process expensive. While the major companies are striving to improve the deposition rate and develop new pretreatment methods, the coating technology itself has also made significant progress.

Roger Bollier, president of multi-layer diamond diamond tool coating LLC (), said: "In the beginning, only single-layer polycrystalline diamond could be formed on the tool."
Bollier said: "But recent technological advances have made it possible to form nanocrystalline diamonds. Nanoscale crystal structures can produce very smooth surfaces and maintain a sharp edge, which can greatly reduce delamination when processing carbon fiber composites."
He added: "The combination of polycrystalline and nanocrystalline diamonds as an interlocking layer produces the best diamond coating, and multi-layered diamond coatings have become an option for all non-ferrous coatings."
The multi-layered nanocrystalline diamond improves the fracture toughness of the coating. In addition, the sub-micron crystals' micro-grain structure can create a smooth surface on the cutting edge for fine surface finishes, which can reduce the formation of built-up edge when processing sticky non-ferrous metals. These coatings can also extend tool life when dry or with minimal lubrication of aluminum alloys.
A common failure of all coatings is cracking. That kind of high and independent polycrystalline diamond structure tends to produce cracks along the fracture lines that directly enter the matrix. Once this problem occurs with the coating, the entire coating will peel off.
However, nanocrystalline diamond cracks at an angle of 45 degrees with the substrate. The staggered layers of polycrystalline and nanodiamond crystals constantly change the direction of the cracks formed during processing, thereby increasing the lifetime of the diamond coating by 40%.

Diamond-coated tool life Diamond-coated tool life is related to the material being cut, cutting speed, feed rate, and part geometry.
In general, graphite diamond-coated tools last 10-20 times longer than uncoated tungsten carbide tools. Therefore, with them, unattended processing can be performed, and a single tool can be used to completely process multiple workpieces. Greatly reduce wear and tool recalibration.
In composite applications, achieving long life is not uncommon. For high-density fiberglass, carbon fiber, and G10-FR4, it has been reported that the life of diamond-coated tools is 70 times the life of uncoated tungsten carbide tools.
Because it takes a long time to coat the tool with diamond, the pretreatment process required to achieve a diamond coated tool with good adhesion is costly.
Although diamond-coated tools cost about five times as much as high-quality carbide tools, they greatly reduce overall production costs because of their wide operating range and long service life. For example, a car manufacturer used a diamond-coated end mill that can process 750 parts worth $150 instead of an end mill capable of processing 15 parts worth $15 when processing high-density fiberglass. The productivity was greatly increased. . This approach saves the company more than $600,000 annually.
As aerospace manufacturers increasingly use composite materials, engineers realized that the right combination of diamond coatings and tool geometries to suit a particular application can provide the most efficient machining solution.
Composite materials such as high-density fiberglass, carbon fiber, and G10-FR4 are easily worn. If the tool is not properly pre-treated, the wear of these materials may reduce the adhesion of the diamond film to cemented carbide.
In an aerospace application, the National Defense Manufacturing and Machining Center (NCDMM) and the Diamond Cutter Coatings LLC were used to process the drive shaft in the Sikorsky Black Hawk helicopter (which consisted of an internal titanium liner, an IM7 carbon fiber tube, and An external titanium end fitting provides a "single pole" solution. This diamond-coated tool can produce high-quality holes at a fraction of the cost of a PCD tool.
In another application, NCDMM and Diamond Tool Coatings developed a diamond tool for machining high-precision sighting systems from the Lockheed Martin missile and fire control companies. Due to the very high tool wear in abrasive applications, it has been difficult for Lockheed to achieve high accuracy. In applications where other coatings are spalled, chemical vapor deposition diamond coatings significantly increase tool life and part machining quality. .

How to Form a Diamond Coating The diamond coating is formed using hydrogen and methane in a vacuum chamber. Typically, these gases are added to the vacuum chamber in a 50:1 ratio, dominated by hydrogen. High temperature elements in the vacuum chamber cause the deposition process to occur. For example, sp3 Inc. () uses filaments heated to about 2,200°C to dissociate the methane into carbon and hydrogen. Then, carbon atoms form nuclei and grow into fine diamond crystals. Over time, these fine crystals form a continuous diamond film. The diamond grows slowly, about 0.5 to 1.0 microns per hour.
It takes almost two days to grow a 40 micron film on a blade, and most round knives require one night for coating.

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